2,7-Dibromo-9-octyl-9H-carbazole

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2,7-Dibromo-9-octyl-9H-carbazole

In the crystal structure of the title compound, C(20)H(23)Br(2)N, the octyl chains are extended in an anti conformation and form a segregating bilayer, isolating rows of carbazole units. The carbazole moieties are engaged in offset π-π inter-actions; the smallest centroid-to-centroid distance is 4.2822 (11) Å. This offset packing motif allows the methyl-ene group attached directly to the N atom...

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3,6-Dibromo-9-(4-chloro­benz­yl)-9H-carbazole

The title compound, C(19)H(12)Br(2)ClN, was synthesized by N-alkyl-ation of 1-chloro-4-(chloro-meth-yl)benzene with 3,6-dibromo-9H-carbazole. The carbazole ring system is essentially planar (mean deviation of 0.028 Å) and makes a dihedral angle of 74.6 (3)° with the plane of the benzene ring.

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3,6-Dibromo-9-(4-bromo­benz­yl)-9H-carbazole

The title compound, C(19)H(12)Br(3)N, was synthesized by N-alkyl-ation of 1-bromo-4-(bromo-meth-yl)benzene with 3,6-dibromo-9H-carbazole. There are two unique mol-ecules in the asymmetric unit. The carbazole ring system is essentially planar, with a mean deviation of 0.0402 Å for one mol-ecule and 0.0279 Å for the other. The carbazole planes are inclined to the benzene ring planes at dihedral a...

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1,1′-(9-Octyl-9H-carbazole-3,6-di­yl)diethanone

The central structural element of the title compound, C(24)H(29)NO(2), is a carbazole unit substituted with two acetyl residues and an octyl chain. The acetyl residues are nearly coplanar [dihedral angles = 5.37 (14) and 1.0 (3)°] with the carbazole unit which is essentially planar (r.m.s. deviation for all non-H atoms = 0.025 Å). The octyl chain adopts an all-trans conformation. The crystal pa...

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2,7-Bis(2-nitro­phen­yl)-9-octyl-9H-carbazole

The title compound, C(32)H(31)N(3)O(4), was obtained in a Suzuki coupling of carbazole diboronic acid and bromo-nitro-benzene. In the crystal, the mol-ecule adopts a non-symmetric conformation. The carbazole ring system is approximately planar [maximum deviation from the least-squares plane = 0.039 (2) Å]. The planes of the carbazole unit and the benzene rings subtend dihedral angles of 48.42 (...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808032121